Question: I typically deal with
both epoxy and acrylic systems. Do you have any tips for making my adhesives
fire retardant?
Answer: Fire retardants have historically been
based on either inorganic materials or halogenated organic compounds. The
entire subject of fire retardancy has been hotly debated in recent years
because of the negative environmental aspects concerned with certain brominated
materials. Phosphate and phosphonate compounds are typical alternative
flame-retardants that do not make use of halogens. In adhesives, the choice of
fire retardants is dependent on the type of system you are using. In a typical
filled epoxy system, you can almost certainly use a combination of a solid
inorganic fire retardant such as aluminum trihydate or magnesium hydroxide,
perhaps supplemented by an organic one. However, if you have an unfilled
acrylic system, particularly one with low viscosity, the choice of materials is
much more limited. In this case, you might consider the handful of brominated
or phosphorous-containing monomers that can be co-polymerized into the
adhesive. There are several suppliers who specialize in fire retardants, and
they can advise you on both product performance and safety aspects.
Question: What sort of approvals do I need for
sealants used on pipes carrying potable water?
Answer: Sealants for contact with drinking water must be certified to a
national standard called ANSI/NSF Standard 61. Several organizations are
accredited by ANSI (American National Standards Institute) to test and certify
this sort of product. The testing involves exposing the cured sealant to
standardized test waters at specified temperatures and times and analyzing the
extraction water for target contaminants. Results of this laboratory testing
are then “normalized” to estimate their concentrations in specific pipe sizes
or tanks, and a material will normally be certified for specific sizes and for
specific water temperature use, defined as commercial hot water (180°F),
“domestic” hot water (140°F), or cold water. The entire process of obtaining
this certification can take many months, and I would advise reading the
standard carefully before initiating testing so that you know the target
contaminants and can determine whether or not your sealant has a good chance of
passing the extraction testing.
Dr. DaveDunn DrDave242@windstream.net Q&A Exchange is written by Dr. Dave Dunn of F.L.D.Enterprises, a technical consultancy and full-service industrial market-research firm specializing in the adhesives, sealants, specialty rubbers and plastics fields. Dr. Dave is a former vice president and director of Loctite Corp. and has spent many years in troubleshooting adhesive and sealant problems. Questions for publication should be directed to him at 242 Trails End, Aurora OH 44202; phone 330-562-2930; fax (330) 247-1690; e-mail DrDave242@windstream.net .