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ColumnsFinished Adhesives and SealantsPressure-Sensitive Adhesives (PSAs)End User Features

Ask Dr. Dave

What has been your experience using silicone caulks, both interior and exterior?

Dave Dunn's December 2016 column.

By Dave Dunn Ph.D.
Dr. Dave
December 1, 2016

Question: What has been your experience using silicone caulks, both interior and exterior?

Answer: Longtime readers of this column may note that I have always been a fan of silicone sealants; however, I worked for a manufacturer of these materials for many years, so I hope I can be totally objective. I have no doubt that the durability and longevity of silicones cannot be exceeded in most applications. However, I can offer you several observations from my personal experience using them at home.

First, you probably know that there are several different types of silicone that differ in their curing chemistry and the byproducts they emit (i.e., the odor as they cure). The oldest are the acetoxy sealants that give off acetic acid (known as a vinegar smell). More modern sealants, such as oxime or alkoxy silicones, release a musty or mild alcohol smell.

I consistently find that the acetoxy silicones give the best adhesion, although they smell the worst. You may also notice mildew and staining on silicones caulks as they age in a moist environment. This, unfortunately, is inevitable; cleaning and drying the joints will slow it down. A major silicone manufacturer once told me that it is possible to make a caulk that is totally resistant to mildew formation, but the mildewcide/fungicide is far too toxic to incorporate in a consumer product.

Many people also have a problem with tooling the silicone after application. Several tools are available, but a wet finger is still the best for me. The real secret is to apply a much narrower bead of product than you think is needed.

Silicones will last longest of all sealants in an outdoor environment, although lack of paintability is a disadvantage. The main alternatives to silicones are acrylic latex caulks. They don’t have the durability or flexibility of silicones, but acrylic latex caulks are somewhat easier to tool, easily clean up with water, and can be painted readily. ASI


Any views or opinions expressed in this column are those of the author and do not represent those of ASI, its staff, Editorial Advisory Board or BNP Media.

KEYWORDS: caulks sealants in construction silicones

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Dave dunn

Ask Dr. Dave is written by Dave Dunn, Ph.D., of F.L.D. Enterprises, a technical consultancy and full-service industrial market-research firm specializing in the adhesives, sealants, specialty rubbers and plastics fields. Dave is a former vice president and director of Loctite Corp. and has spent many years in troubleshooting adhesive and sealant problems. Questions for publication should be directed to him at 242 Trails End, Aurora OH 44202; phone (440) 477-5164; fax (330) 247-1690; or email DrDave242@windstream.net .

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