Adhesives Mag logo
search
cart
facebook twitter linkedin youtube
  • Sign In
  • Create Account
  • Sign Out
  • My Account
Adhesives Mag logo
  • NEW PRODUCTS
  • NEWS
    • Adhesives & Sealants Headlines
    • Mergers/Acquisitions
    • Market Trends
    • TOP 20
  • TOPICS
    • Finished Adhesives and Sealants
    • Pressure-Sensitive Adhesives (PSAs)
    • Coatings
    • Raw Materials and Chemicals
    • Materials Handling/Processing
    • Meter/Mix/Dispense
    • Curing
    • Testing/Quality Control
    • Packaging of Adhesives & Sealants
    • Converting/Packaging
    • Composites
    • Sustainability
  • EVENTS
    • MAX
    • ASI Academy
    • Events Calendar
  • COLUMNS
    • European Perspectives
    • Strategic Solutions
    • Supply Chain Strategies
    • Tape Talk
  • MULTIMEDIA
    • Videos
    • Podcasts
    • Webinars
    • eBooks
  • EXPLORE
    • Adhesives in Action
    • Blog
    • ASI Store
    • Industry Links
    • Market Research
    • Classifieds
  • DIRECTORIES
    • Buyers' Guide
    • Global Adhesives & Sealants Directory
    • Raw Materials, Chemicals, Polymers and Additives Handbook
    • Equipment Handbook
    • Distributor Directory
  • EMAGAZINE
    • EMAGAZINE
    • ARCHIVE ISSUES
    • ADVERTISE
      • Custom Content & Marketing Services
    • CONTACT
  • SIGN UP!
Adhesives and Sealants TopicsColumnsFinished Adhesives and SealantsRaw Materials and Chemicals

Ask Dr. Dave

Why do monomers from different suppliers result in different cure speeds and stabilities for anaerobic adhesives?

Dr. Dave tackles the effect that monomers can have on anaerobic adhesives formulations.

By Dave Dunn Ph.D.
Dr. Dave
June 24, 2019

I started my career as a chemist with Loctite Corp., and we used to manufacture our own monomers. Quite frankly, it was a problem until we discovered how to stabilize them in a consistent fashion. This was achieved by using the correct levels of free radical stabilizers and metal chelators. These adhesives contain initiators and accelerators, which are usually hydroperoxides and aromatic amines. When the adhesives are applied and come in contact with metallic surfaces like iron or copper, these initiation systems generate free radicals that polymerize the monomers to give cured products.

In your case, it looks like your monomers may have different stabilizers or stabilizers at different levels. The most common free radical stabilizers are hydroquinone or methoxy hydroquinone (MEHQ). Check the certificates of analysis from your suppliers; they should list the stabilizer content.

I would also suggest that you look at the strong possibility that there are traces of iron or copper in the monomers, perhaps residues from your suppliers’ manufacturing equipment. Traces of these metals are the real enemy of the anaerobic adhesives formulator, and you should ask your suppliers to remove them or complex them with a metal chelator. You can also treat your monomers by stirring them over EDTA or adding very small amounts of a slightly soluble chelator such as tetrasodium EDTA.
 


Any views or opinions expressed in this column are those of the author and do not represent those of ASI, its staff, Editorial Advisory Board or BNP Media.

KEYWORDS: bonding

Share This Story

Looking for a reprint of this article?
From high-res PDFs to custom plaques, order your copy today!

Dave dunn

Ask Dr. Dave is written by Dave Dunn, Ph.D., of F.L.D. Enterprises, a technical consultancy and full-service industrial market-research firm specializing in the adhesives, sealants, specialty rubbers and plastics fields. Dave is a former vice president and director of Loctite Corp. and has spent many years in troubleshooting adhesive and sealant problems. Questions for publication should be directed to him at 242 Trails End, Aurora OH 44202; phone (440) 477-5164; fax (330) 247-1690; or email DrDave242@windstream.net .

Recommended Content

JOIN TODAY
to unlock your recommendations.

Already have an account? Sign In

  • mouse in hole

    Using Foam Sealants for Pest Prevention

    According to the National Pest Management Association,...
    Finished Adhesives and Sealants
    By: Kevin Corcoran
  • linked network nodes

    Using the Power of AI for Adhesive and Sealant Formulation

    With the help of software solutions, adhesive formulators...
    Finished Adhesives and Sealants
    By: Karen Parker
  • top20-hero.jpg

    2024 ASI Top 20: Leading Global Manufacturers of Adhesives and Sealants

    ASI's annual ranking of the top 20 global adhesive and...
    Pressure-Sensitive Adhesives (PSAs)
Manage My Account
  • eMagazine Issues
  • Newsletters
  • Online Registration
  • Manage My Preferences
  • Subscription Customer Service

More Videos

Popular Stories

image of a graph representing markets

Sika Announces Acquisition of Gulf Seal in Saudi Arabia

Picture of two men and one woman in dark suits

Bodo Möller Chemie Makes Management Change for CASE Business Unit

news on internet screen

Henkel Posts Positive Organic Growth for Third Quarter, Driven by Adhesives Technologies Business

ASI Top 20 website

Events

January 1, 2030

Webinar Sponsorship Information

For webinar sponsorship information, visit www.bnpevents.com/webinars or email webinars@bnpmedia.com.

View All Submit An Event

Products

Structural Adhesives: Properties, Characterization and Applications

Structural Adhesives: Properties, Characterization and Applications

See More Products

ASI CASE EBOOK

Related Articles

  • Dr. Dave

    How do we increase the thermal resistance of anaerobic adhesives?

    See More
  • Dr. Dave

    How do I disassemble nuts and bolts that were assembled using anaerobic threadlockers, then re-use the fasteners?

    See More
  • Dr. Dave

    What type of adhesives would you recommend for bonding glass to steel that will be exposed from -20-100˚F in an outdoor environment?

    See More

Related Products

See More Products
  • 4.png

    Progress in Adhesion and Adhesives, Volume 7

See More Products

Events

View AllSubmit An Event
  • July 18, 2012

    Why VOC Content Minimization Does Not Yield Low VOC Emissions

    Informative webinar covers the science behind why VOC content IS different than VOC emissions.
View AllSubmit An Event

Related Directories

  • Ingredients + Specialties from Univar Solutions

    Ingredients + Specialties from Univar Solutions, a global provider of specialty ingredients and chemicals, serves the coatings, adhesives, sealants, and elastomers markets, including solutions for other performance materials. We empower our customers and suppliers with specialty ingredients, solutions, and technical expertise through our global Solution Centers, focusing on CASE industry innovations.
×

Keep the info flowing with our newsletters!

Get the latest industry updates tailored your way.

JOIN TODAY!
  • RESOURCES
    • Advertise
    • Contact Us
    • Directories
    • Manufacturing Division
    • Store
    • Want More
  • SIGN UP TODAY
    • Create Account
    • eMagazine
    • Newsletters
    • Customer Service
    • Manage Preferences
  • SERVICES
    • Marketing Services
    • Reprints
    • Market Research
    • List Rental
    • Survey & Sample
  • STAY CONNECTED
    • LinkedIn
    • Facebook
    • Youtube
    • X (Twitter)
  • PRIVACY
    • PRIVACY POLICY
    • TERMS & CONDITIONS
    • DO NOT SELL MY PERSONAL INFORMATION
    • PRIVACY REQUEST
    • ACCESSIBILITY

Copyright ©2025. All Rights Reserved BNP Media.

Design, CMS, Hosting & Web Development :: ePublishing